By Michael P. Doyle
Presents the main cutting edge leads to carbene chemistry, environment the basis for brand spanking new discoveries and applications
The discovery of strong carbenes has reinvigorated carbene chemistry examine, with investigators looking to advance carbenes into new necessary catalysts and ligands. offering the main cutting edge and promising parts of carbene study during the last decade, this ebook explores newly came across structural, catalytic, and organometallic features of carbene chemistry, with an emphasis on new and rising artificial applications.
Contemporary Carbene Chemistry good points contributions from a global group of pioneering carbene chemistry researchers. jointly, those authors have highlighted the main attention-grabbing and promising components of research within the box. The e-book is split into parts:
- Part 1, homes and Reactions of Carbenes, explores new findings on carbene balance, acid-base habit, and catalysis. Carbenic constitution and reactivity are tested in chapters devoted to sturdy carbenes, carbodicarbenes, carbenes as site visitors in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited country precursors. Theoretical matters are addressed in chapters on computational tools and dynamics utilized to carbene reactions.
- Part 2, steel Carbenes, is devoted to the factitious dimensions of carbenes, really the reactions and catalytic houses of steel carbenes. The authors speak about lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold.
All the chapters finish with a precis of the present state of affairs, new demanding situations at the horizon, and promising new learn instructions. an inventory of key stories and recommendations for additional examining additionally accompanies each chapter.
Each quantity of the Wiley sequence on Reactive Intermediates in Chemistry and Biology makes a speciality of a selected reactive intermediate, supplying a extensive variety of views from major specialists that units the level for brand new functions and additional discoveries.
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